NICOLA Sturgeon will tomorrow set off for Brussels in her bid to keep Scotland inside the EU.

The First Minister has secured a meeting with the President of the European Parliament, Martin Schulz, as she embarks on an unprecedented diplomatic initiative for the head of a devolved UK administration.

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Jean-Claude Juncker, the President of the European Commission, will not meet with the SNP leader as he is "tied up" with council business and will then be setting off for Slovakia. However, the Scottish Government expects to arrange a summit with Mr Junker in the coming weeks.

Ms Sturgeon has acted quickly in her bid to secure support from EU institutions and other member states following last week's referendum, which saw Scotland vote overwhelmingly to remain in the bloc but the UK wide result in favour of leaving.

Her spokesman confirmed that Ms Sturgeon remains convinced that another independence referendum is "highly likely", ahead of a statement to the Scottish Parliament this afternoon. It is expected that she will unveil the make-up of an expert panel, which is being set up to provide advice on ways in which the country can hold on to its EU status, in her speech to MSPs.

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On her trip she is also expected to secure meetings with prominent members of European parliamentary groups, including former Belgian Prime Minister Guy Verhofstadt, who leads the Group of the Alliance of Liberals and Democrats for Europe in Brussels.

The bi-lateral talks are taking place without any representation of the UK Government. It is customary for the Foreign Office to have involvement in major foreign visits involving heads of devolved administrations.

Ms Sturgeon's spokesman, speaking following a meeting the cabinet, said: "This is all about finding what solutions might be available in completely unchartered territory... we are intent on finding the best possible outcome for Scotland to retain her EU status in line with the democratically expressed wish of the people in Scotland.

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"What that may or may not entail is the matter for discussion, the mechanism that might be available. No-one has ever been in this situation before, no country has ever essentially booted itself out of the EU before."

News of the trip emerged shortly after SNP MEP Alyn Smith received a rare standing ovation on the floor of the European Parliament after he urged fellow members to stand by Scotland in its quest to retain EU membership.

He said: "I represent Scotland within this house and where I’m proudly Scottish, I’m also proudly European. I want my country to be internationalist, cooperative, ecological, fair, European – and the people of Scotland along with the people of Northern Ireland and the people of London and lots and lots of people in Wales and England also voted to remain within our family of nations. I demand that that status and that esprit européen be respected.

"Colleagues, there are a lot of things to be negotiated and we will need cool heads and warm hearts, but please remember this: Scotland did not let you down. Please, I beg you, cher colleagues, do not let Scotland down now."